Nitrogen and sulfur co-doped graphene supported PdW alloys as highly active electrocatalysts for oxygen reduction reaction
Nitrogen and sulfur co-doped graphene supported PdW alloys as highly active electrocatalysts for oxygen reduction reaction
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氮硫共掺杂石墨烯负载PdW合金作为氧还原反应高活性电催化剂
DOI:
10.1016/j.ijhydene.2018.01.093
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发表时间:
2018-03
影响因子:
7.2
通讯作者:
Ren Xiangzhong
中科院分区:
文献类型:
--
作者:
Sun Xiang;Li Wanhui;Mi Hongwei;Li Yongliang;Zhang Peixin;Ren Xiangzhong
Nitrogen and sulfur co-doped graphene (NSG) is prepared by a facile microwave irradiation method and palladium-tungsten (PdW) alloy nanoparticles are supported on the NSG substrate. Several techniques, including X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, cyclic voltammetry and scanning electrochemical microscopy etc. are used to characterize the physical and electrochemical properties of the as-prepared samples. It is found that the PdW alloy nanoparticles are uniformly dispersed on the surface of NSG and the electrochemical performance of PdW/NSG is much better than those of Pd/NSG and Pd/G. The reason for the improved electrochemistry performance of PdW/NSG is considered to be the strong interactions and synergetic effects between PdW nanoparticles and NSG.
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