Transformation of a metal-organic framework from the NbO to PtS net.
Transformation of a metal-organic framework from the NbO to PtS net.
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DOI：
10.1021/ic048612y
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发表时间：
2004-12
影响因子：
4.6
通讯作者：
Banglin Chen;N. W. Ockwig;F. Fronczek;D. Contreras;O. Yaghi
中科院分区：
文献类型：
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作者：
Banglin Chen;N. W. Ockwig;F. Fronczek;D. Contreras;O. Yaghi
两种金属有机骨架（mof）， MOF-501和MOF-502，分别被配制成Co(2)(BPTC)(H(2)O)(5)。G(x)和Co(2)(BPTC)(H(2)O)（DMF)(2)）。G(x) （BPTC = 3,3',5,5'-联苯四羧酸酯；G =客体分子）的合成和结构表征，发现它们的拓扑结构是基于NbO （MOF-501）和PtS （MOF-502）网。在溶液中加热MOF-501会得到热力学上更有利的MOF-502。
Two metal-organic frameworks (MOFs), MOF-501 and MOF-502, respectively, formulated as Co(2)(BPTC)(H(2)O)(5).G(x) and Co(2)(BPTC)(H(2)O)(DMF)(2).G(x) (BPTC = 3,3',5,5'-biphenyltetracarboxylate; G = guest molecules), have been synthesized and structurally characterized, and their topologies were found to be based on the NbO (MOF-501) and PtS (MOF-502) nets. Heating MOF-501 in solution results in the more thermodynamically favored MOF-502.