Iodine-induced electrical conductivity of novel columnar lanthanide metal–organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand
Iodine-induced electrical conductivity of novel columnar lanthanide metal–organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand
复制标题
基于蝴蝶形α-延伸四硫富瓦烯配体的新型柱状镧系金属有机框架的碘诱导电导率
DOI：
10.1039/d2ma00606e
复制
发表时间：
2022
影响因子：
5
通讯作者：
Saha, Sourav
中科院分区：
文献类型：
--
作者：
Gordillo, Monica A.;Benavides, Paola A.;McMillen, Colin;Saha, Sourav
合成了基于蝴蝶形富电子四硫富瓦烯配体的新型柱状稀土金属有机骨架(Ln-MOF)，并研究了它们的电子性质。在碘诱导的配体氧化作用下，TB-MOF的电导率(5×10−7 S m−1)比中性原始MOF高约100倍。
Novel columnar lanthanide metal–organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10−7 S m−1) than the neutral pristine MOF.