N-substituted imines by the copper-catalyzed N-imination of boronic acids and organostannanes with O-acyl ketoximes
N-substituted imines by the copper-catalyzed N-imination of boronic acids and organostannanes with O-acyl ketoximes
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DOI：
10.1021/ol070561w
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发表时间：
2007-05-10
期刊：
影响因子：
5.2
通讯作者：
Liebeskind, Lanny S.
中科院分区：
文献类型：
--
作者：
Liu, Songbai;Yu, Ying;Liebeskind, Lanny S.
催化量的铜（I）或铜（II）源通过在非碱性条件下与肟O-羧酸酯反应来催化硼酸和有机锡烷的N-亚胺化。该方法容许各种官能团，并且使用芳基、杂芳基和烯基硼酸和锡烷有效地进行。
Catalytic quantities of copper(I) or copper(II) sources catalyze the N-imination of boronic acids and organostannanes through reaction with oxime O-carboxylates under nonbasic conditions. This method tolerates various functional groups and takes place efficiently using aryl, heteroaryl, and alkenyl boronic acids and stannanes.