Polyrotaxane and Slide-Ring Materials
Polyrotaxane and Slide-Ring Materials
复制标题
聚轮烷和滑环材料
DOI：
10.1039/9781782622284
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发表时间：
2015
期刊：
影响因子：
--
通讯作者：
Kazuaki Kato
中科院分区：
文献类型：
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作者：
K. Mayumi;K. Ito;Kazuaki Kato
聚轮烷是一种项链状超分子，其中许多环状分子串成单个聚合物链，并且可以交联以生产功能聚合物材料。所得材料具有可移动的交联，具有不同于其他具有固定共价键的聚合物网络的独特性能，在新型薄膜、弹性体和涂料中受到广泛关注。聚轮烷和滑环材料是第一本涵盖这些分子和材料的基础知识和应用的书。在概述之后，本书的第一部分介绍了聚轮烷中包合物形成和滑动转变的热力学，然后介绍了聚轮烷和滑环材料的不同合成技术。然后，本书介绍了用于结构分析的不同散射方法，然后是有关聚轮烷的电学和光学性质以及滑环材料的机械和热力学性质的章节。本书的最后部分包含有关其应用的不同章节，包括凝胶弹性体和树脂。该书由滑环材料的发明者撰写，将吸引超分子化学、高分子化学和高分子物理学领域的学生、研究人员和工程师。
Polyrotaxane is a necklace-like supramolecule in which many cyclic molecules are threaded into a single polymer chain and can be cross-linked to produce functional polymeric materials. The resulting materials have movable cross-linking giving unique properties different from other polymer networks with fixed covalent bonds gaining much attention for new films, elastomers and coatings. Polyrotaxane and Slide-Ring Materials is the first book to cover the fundamentals and applications of these molecules and materials. After a general introduction, the first part of the book covers the thermodynamics of inclusion complex formation and sliding transition in polyrotaxane, followed by different synthesis techniques of polyrotaxane and slide-ring materials. The book then addresses different scattering methods for structural analysis followed by chapters on the electric and optical properties of polyrotaxane as well as the mechanical and thermodynamic properties of slide-ring materials. The final part of the book contains different chapters on their applications including gels elastomers and resins. Authored by the inventor of slide-ring materials, it will appeal to students, researchers, and engineers in supramolecular chemistry, polymer chemistry and polymer physics.