CRYSTAL-STRUCTURE AND MOLECULAR STEREOCHEMISTRY OF MU-OXO-BIS[ALPHA, BETA, GAMMA, DELTA-TETRAPHENYLPORPHINATOIRON(III)]
CRYSTAL-STRUCTURE AND MOLECULAR STEREOCHEMISTRY OF MU-OXO-BIS[ALPHA, BETA, GAMMA, DELTA-TETRAPHENYLPORPHINATOIRON(III)]
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DOI：
10.1021/ja00765a060
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发表时间：
1972-01-01
影响因子：
15
通讯作者：
COLLINS, DM
中科院分区：
文献类型：
--
作者：
HOFFMAN, AB;HOARD, JL;COLLINS, DM
β-氧代-双[α，β，3，7，5-四苯基卟啉合铁（III）]晶体具有Clca-Civ 11空间群对称性，晶胞参数为a= 15，197（5），B= 25.077（12），c= 18.074（6）π，含有4个低聚分子，O（FeTPP）2;相应的计算和实验密度为1.30和1.28gcm-3。结构的测定和最小二乘精修利用了约3501个独立的反测强度数据
Crystals of^-oxo-bis [a,/3, 7, 5-tetraphenylporphinatoiron (III)] observe the space group symmetry of Clca-Civ11; the unit cell has a= 15,197 (5), b= 25.077 (12), and c= 18.074 (6) Á, and contains four oligomeric molecules, 0 (FeTPP) 2; the respective calculated and experimental densities are 1.30 and 1.28 g cm-3. Determina-tion and least-squares refinement of structure utilized some 3501 independent, counter-measured, intensity data