A simple and general preparation of vinylic sulfides, selenides and tellurides

A simple and general preparation of vinylic sulfides, selenides and tellurides
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DOI:
10.1016/j.jorganchem.2008.09.039
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发表时间:
2008-12-15
影响因子:
2.3
通讯作者:
Braga, Antonio L.
Braga, Antonio L.
中科院分区:
化学3区
文献类型:
--
作者:
Silveira, Claudio C.;Santos, Paulo Cesar S.;Braga, Antonio L.

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A general method for the synthesis of vinylic chalcogenides by nucleophilic and Ni-catalyzed vinylic substitution on vinylic halides by phenyl chalcogenolates is described. The reactions were regio and stereo-selective for the nickel catalyzed substitution, and mixture of isomers was observed for some examples in the thermal process in DMF. (C) 2008 Elsevier B.V. All rights reserved.