Silylation of Aryl Iodides with 1,1,1,3,5,5,5-Heptamethyltrisiloxane Catalyzed by Transition-Metal Complexes
Silylation of Aryl Iodides with 1,1,1,3,5,5,5-Heptamethyltrisiloxane Catalyzed by Transition-Metal Complexes
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DOI：
10.1055/s-2007-980343
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发表时间：
2007-06
期刊：
影响因子：
2
通讯作者：
Miki Murata;Kosuke Ota;Hiroyuki Yamasaki;Shinji Watanabe;Y. Masuda
中科院分区：
文献类型：
--
作者：
Miki Murata;Kosuke Ota;Hiroyuki Yamasaki;Shinji Watanabe;Y. Masuda
通过合适的过渡金属催化剂，如Pd(0)、Pt(0)和Rh(I)，实现了各种芳基碘化物与1,1,1,3,5,5,5-七甲基三硅氧烷的甲硅烷基化。这些催化系统表现出显着不同的底物范围。
The silylation of various kinds of aryl iodides with 1,1,1,3,5,5,5-heptamethyltrisiloxane was achieved by a suitable transition-metal catalyst, such as Pd(0), Pt(0), and Rh(I). These -catalytic systems showed dramatically different substrate scope.