Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst
Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst
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用于评估底物识别氧化催化剂的区域选择性的亚甲基链标尺
DOI：
10.1039/c9cc03041g
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发表时间：
2019
影响因子：
4.9
通讯作者：
Higuchi Tsunehiko
中科院分区：
文献类型：
--
作者：
Teramae Shota;Kito Akane;Shingaki Tomoteru;Hamaguchi Yu;Yano Yuuki;Nakayama Takamori;Kobayashi Yuko;Kato Nobuki;Umezawa Naoki;Hisamatsu Yosuke;Nagano Tetsuo;Higuchi Tsunehiko
用合成催化剂对脂肪族分子进行区域选择性C-H氧化具有挑战性。我们在钌卟啉-杂环氮氧化物催化体系中引入底物识别位点，以提高其对烷烃氧化的区域选择性。这种底物识别催化反应具有高的区域选择性和高的反应效率。
Regioselective C–H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin–heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.