An efficient method for the synthesis of enol ethers and enecarbamates. Total syntheses of isoindolobenzazepine alkaloids, lennoxamine and chilenine
An efficient method for the synthesis of enol ethers and enecarbamates. Total syntheses of isoindolobenzazepine alkaloids, lennoxamine and chilenine
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DOI：
10.1039/b706087d
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发表时间：
2007-01-01
影响因子：
3.2
通讯作者：
Sasaki, Makoto
中科院分区：
文献类型：
--
作者：
Fuwa, Haruhiko;Sasaki, Makoto
基于α-膦氧基烯醇醚和α-膦氧基烯氨基甲酸酯的硅氢催化还原反应，开发了一种合成烯醇醚和烯氨基甲酸酯的有效方法。该方法已应用于两种异吲哚苯并氮卓生物碱的全合成。
An efficient method for the synthesis of enol ethers and enecarbamates has been developed based on catalytic hydrosilane reduction of alpha-phosphonoxy enol ethers and alpha-phosphonoxy enecarbamates. This method has been applied to the total syntheses of two isoindolobenzazepine alkaloids, lennoxamine and chilenine.