An ordered mesoporous aluminosilicate with completely crystalline zeolite wall structure

An ordered mesoporous aluminosilicate with completely crystalline zeolite wall structure
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DOI:
10.1021/ja061182l
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发表时间:
2006-08-23
影响因子:
15
通讯作者:
Hu, Haoquan
Hu, Haoquan
中科院分区:
化学1区
文献类型:
--
作者:
Fang, Yunming;Hu, Haoquan

文献摘要

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以原位合成的CMK-5为硬模板剂,通过重结晶SBA-15,成功合成了具有完全晶化沸石孔壁结构的有序介孔硅铝酸盐(OMZ-1)。碳材料的作用不仅作为硬模板来保持有序的介孔结构,而且还在动力学上控制结晶过程以形成大晶体。
An ordered mesoporous aluminosilicate with completely crystalline zeolite pore wall structure, denoted as OMZ-1, was successfully synthesized by recrystallization of SBA-15 using in situ formed CMK-5 as the hard template. The role of carbon material not only serves as a hard template to preserve ordered mesoporous structure but also kinetically controls the crystallization process to form large crystals.