Palladium-Catalyzed Amination of 2,3,3-Trifluoroallyl Esters: Synthesis of Trifluoromethylenamines by the Intramolecular Fluorine Shift and CF3 Group Construction
Palladium-Catalyzed Amination of 2,3,3-Trifluoroallyl Esters: Synthesis of Trifluoromethylenamines by the Intramolecular Fluorine Shift and CF3 Group Construction
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钯催化 2,3,3-三氟烯丙酯的胺化：通过分子内氟位移和 CF3 基团构建合成三氟亚甲基胺
DOI：
10.1039/c5cc01212k
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发表时间：
2015
期刊：
影响因子：
--
通讯作者：
M.
中科院分区：
文献类型：
--
作者：
Isa;K.; Minakawa;M.; Kawatsura;M.
钯催化的2，3，3-三氟烯丙基酯与几种类型的胺的反应得到三氟亚甲基胺，其通过在C-2位添加氮亲核试剂和通过氟原子从C-2位移动到C-3位形成三氟甲基的分子内结构而形成。
The palladium-catalyzed reaction of 2,3,3-trifluoroallyl esters with several types of amines afforded trifluoromethylenamines, which were formed by the addition of a nitrogen nucleophile at the C-2 position and the intramolecular construction of the trifluoromethyl group via the fluorine atom shift from the C-2 to the C-3 position.