Synthesis and magnetic properties of N@C60 derivatives

Synthesis and magnetic properties of N@C60 derivatives
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DOI:
10.1016/j.cplett.2006.02.046
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发表时间:
2006-04-28
影响因子:
2.8
通讯作者:
Maggini, M
Maggini, M
中科院分区:
化学4区
文献类型:
--
作者:
Franco, L;Ceola, S;Maggini, M

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我们报道了四种包覆氮原子的内嵌富勒烯单加合物的合成和EPR表征(N@C-60)。通过封闭顺磁性氮原子在四重奏基态下精细结构参数的变化,研究了不同外面体分子结构融合对富勒烯笼的影响。(c) 2006 Elsevier B.V.版权所有
We report on the synthesis and EPR characterization of four new monoadducts of endohedral fullerenes encapsulating a nitrogen atom (N@C-60). The effect of different exohedral molecular structures fused to the fullerene cage is studied through the change of the fine structure parameters of the enclosed paramagnetic nitrogen atom in its quartet ground state. (c) 2006 Elsevier B.V. All rights reserved.