Synthesis of alpha-norbornenylpoly(ethylene oxide) macromonomers and their ring-opening metathesis polymerization
Synthesis of alpha-norbornenylpoly(ethylene oxide) macromonomers and their ring-opening metathesis polymerization
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DOI：
10.1021/ma951797v
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发表时间：
1996-06-17
期刊：
影响因子：
5.5
通讯作者：
Fontanille, M
中科院分区：
文献类型：
--
作者：
Heroguez, V;Breunig, S;Fontanille, M
本工作主要研究了α-降冰片基聚氧乙烯大单体的合成及其开环歧化聚合。虽然以100%的产率获得，摩尔质量分布窄，但聚合物大单体的聚合度比预期的要高。详细讨论了该功能的原因。
This work focuses on the synthesis and the ring-opening metathesis polymerization of alpha-norbornenylpoly(ethylene oxide) macromonomers. Although obtained in 100% yield and with a narrow distribution of molar masses, the polymacromonomers exhibit degrees of polymerization that are systematically higher than expected. The reasons for this feature are thoroughly discussed.