The overall adhesion-spreading process of liposomes on a mercury electrode is controlled by a mixed diffusion and reaction kinetics mechanism

The overall adhesion-spreading process of liposomes on a mercury electrode is controlled by a mixed diffusion and reaction kinetics mechanism
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脂质体在汞电极上的整体粘附扩散过程由混合扩散和反应动力学机制控制

DOI:
10.1007/s10008-008-0639-7
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发表时间:
2009
影响因子:
2.5
通讯作者:
F. Scholz
F. Scholz
中科院分区:
工程技术4区
文献类型:
--
作者:
V. Agmo Hernández;Michael Hermes;A. Milchev;F. Scholz

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采用高分辨率计时电流法,以1.333 μs为采样周期,研究了脂质体在汞电极上粘附-铺展的初始阶段。这些测量允许更深入地了解脂质体与汞电极的第一次相互作用,并且它们表明,在不同电位下的整体粘附扩散过程部分地由快速但弱的相互作用平衡控制,从而导致整体反应的混合扩散和反应动力学控制机制。
Using high-resolution chronoamperometric measurements, with sampling each 1.333 μs, the initial step of the adhesion-spreading of liposomes on a mercury electrode was studied. These measurements allow getting a deeper insight into the first interaction of the liposomes with the mercury electrode, and they show that the overall adhesion-spreading process at different potentials is partially controlled by a fast but weak interaction equilibrium resulting in a mixed diffusion- and reaction-kinetics-controlled mechanism of the overall reaction.
DOI: 10.1016/s0006-3495(02)75274-0
发表时间: 2002-11-01
影响因子: 3.4
作者:
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通讯作者: Kozlov, MM
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