Cationic palladium(II)-catalyzed addition of arylboronic acids to nitriles. One-step synthesis of benzofurans from phenoxyacetonitriles.
Cationic palladium(II)-catalyzed addition of arylboronic acids to nitriles. One-step synthesis of benzofurans from phenoxyacetonitriles.
复制标题
DOI：
10.1021/ol062438v
复制
发表时间：
2006-11
期刊：
影响因子：
5.2
通讯作者：
Baowei Zhao;Xiyan Lu
中科院分区：
文献类型：
--
作者：
Baowei Zhao;Xiyan Lu
【结构：开发了一种阳离子钯络合物催化的芳基硼酸与腈的加成反应，以中等至良好的产率生成芳基酮。以[（bpy）Pd+（micro-OH）]2（-OTf）2或[（bpy）Pd 2+（H2O）2]（-OTf）2为催化剂，由苯氧基乙腈一步合成苯并呋喃。
[Structure: see text] A cationic palladium complex catalyzed addition of arylboronic acids to nitriles to yield aryl ketones with moderate to good yields was developed. A one-step synthesis of benzofurans from phenoxyacetonitriles under the catalysis of [(bpy)Pd+(micro-OH)]2(-OTf)2 or [(bpy)Pd2+(H2O)2](-OTf)2 was developed which showed that the cationic palladium catalyst is highly active for these addition reactions.