Hydrogenation Reactions Catalyzed by PNP-Type Complexes Featuring a HN(CH2CH2PR2)2 Ligand
Hydrogenation Reactions Catalyzed by PNP-Type Complexes Featuring a HN(CH2CH2PR2)2 Ligand
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DOI：
10.1007/3418_2020_63
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发表时间：
2020
期刊：
影响因子：
--
通讯作者：
Dewmi Ekanayake;Hairong Guan
中科院分区：
文献类型：
--
作者：
Dewmi Ekanayake;Hairong Guan
本章首先提供了一个简短的背景氢化机制如何演变多年来导致开花的催化体系与金属配体的协同作用。本章的主体特别关注由HN（CH 2CH 2 PR 2）2型配体支持的络合物。氢化系统的讨论基于中心金属包括Ru、Fe、Os、Rh、Co、Ir、Ni、Pd、Mo、W、Mn和Re（以该特定顺序）来组织。参与这些氢化反应的底物包括烯烃、醛、酮、酯、酰胺、环氧化物、腈、亚胺、N-杂环、CO2（生成甲酸酯或甲醇）、甲硅烷基甲酸酯、CO（生成乙二醇或甲醇）和环状碳酸酯。在适当的情况下，在这些催化体系中的金属配体的协同性的存在或缺乏突出。
This chapter first provides a brief background of how hydrogenation mechanisms have evolved over the years leading to the blossom of catalytic systems with metal-ligand cooperativity. The main body of the chapter focuses specifically on complexes supported by ligands of the type HN(CH2CH2PR2)2. The discussion of hydrogenation systems is organized based on the central metals including Ru, Fe, Os, Rh, Co, Ir, Ni, Pd, Mo, W, Mn, and Re (in that particular order). Substrates involved in these hydrogenation reactions include olefins, aldehydes, ketones, esters, amides, epoxides, nitriles, imines,N-heterocycles, CO2(to formate or methanol), silyl formates, CO (to ethylene glycol or methanol), and cyclic carbonates. When appropriate, the presence or the lack of metal-ligand cooperativity in these catalytic systems is highlighted.