Reactions of Phosphoramidic Acids

Reactions of Phosphoramidic Acids
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磷酰胺酸的反应

DOI:
10.1070/rc1972v041n01abeh002030
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发表时间:
1972
影响因子:
7.7
通讯作者:
N. Preobrazhenskaya
N. Preobrazhenskaya
中科院分区:
化学2区
文献类型:
--
作者:
N. Preobrazhenskaya

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研究了磷酰胺酸的水解和溶解机理。讨论了在酸、醇和胺的磷酸化反应中,作为磷残基供体的磷酰胺酸盐的概念。已经证明了在合成化学中作为磷酸化试剂的磷酸盐的使用,以及它们在生物磷酸化过程中的可能参与。参考文献共142篇。
The mechanisms of the hydrolysis and solvolysis of phosphoramidic acids have been examined. The concepts of phosphoramidates as donors of the phosphate residue in phosphorylation reactions of acids, alcohols, and amines are discussed. The use of phosphoramidates as phosphorylating agents in synthetic chemistry and also their possible involvement in biological phosphorylation processes have been demonstrated. The bibliography includes 142 references.