Bridged eosin Y: a visible and near-infrared photoredox catalyst
Bridged eosin Y: a visible and near-infrared photoredox catalyst
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桥联曙红 Y：可见光和近红外光氧化还原催化剂
DOI：
10.1039/d2cc02907c
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发表时间：
2022
影响因子：
4.9
通讯作者：
Kamino Shinichiro
中科院分区：
文献类型：
--
作者：
Tanioka Masaru;Kuromiya Ayako;Ueda Rina;Obata Tohru;Muranaka Atsuya;Uchiyama Masanobu;Kamino Shinichiro
本文开发了一种新的近红外光氧化还原催化剂--桥连曙红Y（BEY）。通过各种光谱方法、X射线单晶结构分析和密度泛函理论计算，阐明了其详细结构和近红外光学性质。此外，我们展示了在有色试剂和高浓度悬浮液中的光反应，以显示近红外光氧化还原催化反应的优势。
Herein, a new NIR photoredox catalyst, bridged eosin Y (BEY), has been developed. Its detailed structure and NIR optical properties are clarified by using various spectroscopic methods, X-ray single-crystal structure analysis and DFT calculations. In addition, we demonstrate the photoreaction in colored reagents and high-concentration suspensions to show the advantage of NIR photoredox-catalyzed reactions.