Enthalpies and entropies of transfer of electrolytes and ions from water to mixed aqueous organic solvents.
Enthalpies and entropies of transfer of electrolytes and ions from water to mixed aqueous organic solvents.
复制标题
电解质和离子从水转移到混合水性有机溶剂的焓和熵。
DOI：
10.1021/cr010031s
复制
发表时间：
2002
期刊：
影响因子：
62.1
通讯作者：
W. Waghorne
中科院分区：
文献类型：
--
作者：
G. Hefter;Y. Marcus;W. Waghorne
一个广泛的严格评估汇编的标准摩尔的熵和熵的电解质从水到混合的含水有机溶剂的转移。在这次汇编中，重新计算了报告的数值，以获得一个一致的格式，从而能够对数据进行比较。这些全盐数据，然后分裂成个别离子的传递函数，使用适当的超热力学假设。
A wide-ranging critically evaluated compilation of the standard molar enthalpies and entropies of transfer of electrolytes from water to mixed aqueous-organic solvents were shown. For this compilation, the reported values were recalculated to obtain a consistent format that enabled comparisons to be made among the data. These whole-salt data were then split into the transfer functions of the individual ions, using an appropriate extrathermodynamic assumption.