Rhodium and iridium aminoborane complexes: coordination chemistry of BN alkene analogues.
Rhodium and iridium aminoborane complexes: coordination chemistry of BN alkene analogues.
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DOI：
10.1002/anie.200906171
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发表时间：
2010-01
影响因子：
--
通讯作者：
C. Tang;A. Thompson;S. Aldridge
中科院分区：
文献类型：
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作者：
C. Tang;A. Thompson;S. Aldridge
侧面还是侧面？合成了以氨基硼烷（R2 N = BH 2）为配体的铑、铱配合物，并对其结构进行了表征。晶体学测量表明，与等电子烯烃供体相反，配体通过双（邻硼烷）结合基序以末端方式结合（见结构）。© 2010 Wiley-VCH Verlag GmbH and Co. KGaA。
Side-on or end-on? Rhodium and iridium complexes featuring aminoboranes (R2N= BH2) as ligands have been synthesized and structurally characterized. Crystallographic measurements show that the ligands-in contrast to isoelectronic alkene donors-bind in an end-on fashion through a bis(o-borane) binding motif (see structure). (Figure Presented) © 2010 Wiley-VCH Verlag GmbH and Co. KGaA.