A new CuAl–hydrotalcite catalyzed homocoupling reaction of terminal alkynes at room temperature

A new CuAl–hydrotalcite catalyzed homocoupling reaction of terminal alkynes at room temperature
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DOI:
10.1002/aoc.1212
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发表时间:
2007-05
影响因子:
3.9
通讯作者:
Bingchun Zhu;X. Jiang
Bingchun Zhu;X. Jiang
中科院分区:
化学3区
文献类型:
--
作者:
Bingchun Zhu;X. Jiang

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首次制备了CuAl-LDH,并将其应用于多种末端炔的室温均偶联反应中。水滑石主体层中的Cu (II)表现出较高的活性,催化剂可以很容易地回收并重复使用8个循环而不降低催化活性。版权所有©2007 John Wiley & Sons, Ltd
CuAl–LDH has been prepared and applied, for the first time, in the homocoupling reaction of a variety of terminal alkynes at room temperature. The Cu (II) in the host layers of the hydrotalcite exhibits high activity and the catalyst can be easily recovered and reused for eight cycles without depreciation of catalytic activity. Copyright © 2007 John Wiley & Sons, Ltd.