A porphyrin-based microporous network polymer that acts as an efficient catalyst for cyclooctene and cyclohexane oxidation under mild conditions
A porphyrin-based microporous network polymer that acts as an efficient catalyst for cyclooctene and cyclohexane oxidation under mild conditions
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DOI：
10.1016/j.catcom.2017.05.024
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发表时间：
2017-08-01
影响因子：
3.7
通讯作者：
Nakagaki, Shirley
中科院分区：
文献类型：
--
作者：
Antonangelo, Ariana R.;Bezzu, C. Grazia;Nakagaki, Shirley
(五氟苯基)卟啉锰(III)(MnP)和六羟基三蝶烯(HHT)之间的高效二苯并二恶英形成反应提供了一种新型微孔网络聚合物(P1)，该聚合物具有大表面积(1080 m(2) g(-1))，并被证明是一种在温和条件下用于环辛烯和环己烷氧化多相催化的有效固体，并且在许多催化循环中具有高回收和再利用能力。
The highly efficient dibenzodioxin-forming reaction between the (pentafluorophenyl)porphyrin manganese(III) (MnP) and hexahydroxytriptycene (HHT) provide a new microporous network polymer (P1), which demonstrated a large surface area (1080 m(2) g(-1)) and proved to be an efficient solid for heterogeneous catalysis for cyclooctene and cyclohexane oxidation under mild conditions and with high capacity of recovery and reuse in many catalytic cycles.