A Novel Pillar-Layered Organic−Inorganic Hybrid Based on Lanthanide Polymer and Polyomolybdate Clusters: New Opportunity toward the Design and Synthesis of Porous Framework
A Novel Pillar-Layered Organic−Inorganic Hybrid Based on Lanthanide Polymer and Polyomolybdate Clusters: New Opportunity toward the Design and Synthesis of Porous Framework
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DOI：
10.1021/cg049732j
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发表时间：
2005
影响因子：
3.8
通讯作者：
Jian Lü;E. Shen;Yang-guang Li;D. Xiao;E. Wang;Lin Xu
中科院分区：
文献类型：
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作者：
Jian Lü;E. Shen;Yang-guang Li;D. Xiao;E. Wang;Lin Xu
报道了一种史无前例的微孔多钼酸镧[{La(H2O)5(dipic)}{La(H2O)(dipic)}]2{Mo8O26}·10H2O(H_2dipic=吡啶-2，6-二羧酸)1，它是由单个八钼酸盐簇合物柱撑的La-−有机配位聚合物薄片构成的。
An unprecedented microporous lanthanum polymolybdate, [{La(H2O)5(dipic)}{La(H2O)(dipic)}]2{Mo8O26}·10H2O (H2dipic = pyridine-2,6-dicarboxylic acid) 1, which is constructed from lanthanum−organic coordination polymer sheets pillared by individual octamolybdate clusters, is reported.