Copper(I)-promoted palladium-catalyzed cross-coupling of unsaturated tri-n-butylstannane with heteroaromatic thioether
Copper(I)-promoted palladium-catalyzed cross-coupling of unsaturated tri-n-butylstannane with heteroaromatic thioether
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DOI：
10.1021/ol027453o
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发表时间：
2003-03-20
期刊：
影响因子：
5.2
通讯作者：
Guillaumet, G
中科院分区：
文献类型：
--
作者：
Alphonse, FA;Suzenet, F;Guillaumet, G
在间隙钯催化下，乙烯基和芳基锡烷与缺乏电子的杂芳烃进行了交偶联反应。在溴化铜-二甲基硫化配合物的存在下，以甲基硫醚为亲电试剂进行了静止式反应。
GaphicsPalladium-catalyzed cross-coupling of vinyl- and arylstannanes with pi-electron-deficient heteroaromatics was performed in good yields. This Stille-type reaction was carried out with a methylthioether function as an electrophile in the presence of a copper(l) bromide-dimethyl sulfide complex.