Transesterification of various methyl esters under mild conditions catalyzed by tetranuclear zinc cluster
Transesterification of various methyl esters under mild conditions catalyzed by tetranuclear zinc cluster
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DOI：
10.1021/jo800625v
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发表时间：
2008-07-04
影响因子：
3.6
通讯作者：
Mashima, Kazushi
中科院分区：
文献类型：
--
作者：
Iwasaki, Takanori;Maegawa, Yusuke;Mashima, Kazushi
开发了一种新的四核锌簇合物催化酯交换反应。温和的反应条件使得各种官能化底物的反应能够以良好至高产率进行。在无溶剂条件下进行大规模反应，E因子值较低（0.66），表明本催化剂具有较高的环境和经济优势。
A new catalytic transesterification promoted by a tetranuclear zinc cluster was developed. The mild reaction conditions enabled the reactions of various functionalized substrates to proceed in good to high yield. A large-scale reaction under solvent-free conditions proceeded with a low E-factor value (0.66), indicating the high environmental and economical advantage of the present catalysis.