Dynamic kinetic resolution with enzyme and palladium combinations
Dynamic kinetic resolution with enzyme and palladium combinations
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DOI：
10.1016/0040-4039(96)00136-0
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发表时间：
1996-03-11
影响因子：
1.8
通讯作者：
Williams, JMJ
中科院分区：
文献类型：
--
作者：
Allen, JV;Williams, JMJ
某些乙酸烯丙酯的动态动力学拆分是通过酶水解成相应的烯丙醇来实现的。在钯催化剂存在下，乙酸烯丙酯发生外消旋，从而发生动态拆分。
The dynamic kinetic resolution of certain allyl acetates has been achieved by enzymatic hydrolysis to the corresponding allyl alcohols. In the presence of a palladium catalyst, the allyl acetate is racemised, allowing a dynamic resolution to take place.