Relaxation experiments in aqueous solutions of ionic micelles. 1. Theory and experiments on the system water-sodium tetradecyl sulfate-sodium perchlorate
Relaxation experiments in aqueous solutions of ionic micelles. 1. Theory and experiments on the system water-sodium tetradecyl sulfate-sodium perchlorate
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离子胶束水溶液中的弛豫实验。
DOI：
10.1021/j150611a014
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发表时间：
1981
期刊：
影响因子：
--
通讯作者：
M. Kahlweit
中科院分区：
文献类型：
--
作者：
E. Lessner;M. Teubner;M. Kahlweit
一个一致的理论的振幅和时间常数的弛豫实验在水溶液中的离子胶束的基础上，随之而来的应用质量作用定律。该理论不仅适用于纯表面活性剂溶液，而且适用于添加电解质的溶液。它表明，振幅可以计算没有详细的知识的反应机理，强调它们是独立的反应方程。该分析允许一个方便的方法来确定适当的胶束的一些相关的平衡性质，以及它们对强度变量的依赖性。并将理论应用于H/sub 2/O-NaTs（sodium tetradiol sulfate）- NaClO/sub 4/体系的实验结果。从振幅和时间常数的分析得到的参数是在足够的协议彼此。15篇参考文献。
A consistent theory of the amplitudes and time constants of relaxation experiments in aqueous solutions of ionic micelles is presented, based on a consequent application of the Law of Mass Action. The theory is applicable not only to pure surfactant solutions but also to solutions with an added electrolyte. It is shown that the amplitudes can be calculated without detailed knowledge of the reaction mechanism which emphasizes that they are indpendent of the reaction equation. The analysis permits a convenient method to determine some of the relevant equilibrium properties of the proper micelles, as well as their dependence on the intensive varibles. The theory is applied to experimental results on the system H/sub 2/O-NaTs (sodium tetradecyl sulfate)- NaClO/sub 4/. The parameters obtained from the analysis of the amplitudes and the time constants are in sufficient agreement with each other. 15 references.