Amperometric detection of endocrine disruptive alkylphenolic compounds based upon the redox recycling on an alkyl chain-coated electrode

Amperometric detection of endocrine disruptive alkylphenolic compounds based upon the redox recycling on an alkyl chain-coated electrode
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基于烷基链涂层电极氧化还原循环的内分泌干扰性烷基酚化合物的电流检测

DOI:
10.1246/cl.2002.652
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发表时间:
2002
期刊:
影响因子:
--
通讯作者:
Y. Kato
Y. Kato
中科院分区:
--
文献类型:
--
作者:
B. Uno;Y. Kato

文献摘要

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提出了一种基于通过与亚铁氰化物反应连续再生氧化形式二茂铁酚的灵敏检测方法,用于内分泌干扰性烷基酚化合物的 HPLC 分析。 4-叔丁基苯酚 (1) 和 4-壬基苯酚 (7) 的检测限分别为 5.4×10-11 和 9.4×10-11 mol dm-3。
A sensitive detection method based upon continuous regeneration of the oxidized form of the ferrocenoyl phenols by reaction with ferrocyanide is proposed for HPLC analyses of endocrine disruptive alkylphenolic compounds. The detection limits were 5.4×10-11 and 9.4×10-11 mol dm-3 of 4-tert-butylphenol (1) and 4-nonylphenol (7), respectively.