Novel chemosensor for multiple target anions: The detection of F− and CN− ion via different approach

Novel chemosensor for multiple target anions: The detection of F− and CN− ion via different approach
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DOI:
10.1016/j.jfluchem.2015.04.014
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发表时间:
2015-07
影响因子:
1.9
通讯作者:
D. Udhayakumari;S. Velmathi;M. Boobalan
D. Udhayakumari;S. Velmathi;M. Boobalan
中科院分区:
化学4区
文献类型:
--
作者:
D. Udhayakumari;S. Velmathi;M. Boobalan

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采用简单缩合法合成了一种基于偶氮连接席夫碱(受体1)的新型化学传感器。受体1的传感器研究揭示了对氟离子和氰化物离子的选择性,在水介质中其他常见阴离子中有颜色变化。通过1h NMR滴定和DFT计算,揭示了受体1的结合亲和力。
A novel chemosensor based on azo linked Schiff base (receptor1) was synthesized by simple condensation method. The sensor studies of receptor1disclose the selectivity toward fluoride and cyanide ion with a color change among the other common anions in aqueous medium. The binding affinity of receptor1was also enlightened by1H NMR titration and DFT calculation.