Microwave-assisted cationic ring-opening polymerization of 2-oxazolines.
Microwave-assisted cationic ring-opening polymerization of 2-oxazolines.
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DOI：
10.1007/12_2015_340
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发表时间：
2015-10-28
期刊：
影响因子：
--
通讯作者：
Wiesbrock F
中科院分区：
文献类型：
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作者：
Luef KP;Hoogenboom R;Schubert US;Wiesbrock F
与任何其他聚合物类别不同，（共）聚（2-恶唑啉）从化学实验室引入微波反应器中受益匪浅。本综述重点关注微波辅助合成（共）聚（2-恶唑啉）领域的研究活动，相应地总结了微波辅助合成 2-恶唑啉单体和微波辅助开环（共）聚合 2-恶唑啉的最新技术以及 (共)聚(2-恶唑啉)的后聚合改性。特别关注2-恶唑啉微波辅助聚合的动力学分析和非热微波效应的讨论。
Unlike any other polymer class, the (co-)poly(2-oxazoline)s have tremendously benefited from the introduction of microwave reactors into chemical laboratories. This review focuses on the research activities in the area of (co-)poly(2-oxazoline)s prepared by microwave-assisted syntheses and, correspondingly, summarizes the current-state-of the-art of the microwave-assisted synthesis of 2-oxazoline monomers and the microwave-assisted ring-opening (co-)polymerization of 2-oxazolines as well as prominent examples of post-polymerization modification of (co-)poly(2-oxazoline)s. Special attention is attributed to the kinetic analysis of the microwave-assisted polymerization of 2-oxazolines and the discussion of non-thermal microwave effects.