Effect of Hydrolysis Catalysts on Structural Evaluation of Sol-Gel Derived Titania Nanocrystalline Powders

Effect of Hydrolysis Catalysts on Structural Evaluation of Sol-Gel Derived Titania Nanocrystalline Powders
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水解催化剂对溶胶-凝胶法二氧化钛纳米晶粉末结构评价的影响

DOI:
10.1088/0256-307x/12/2/017
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发表时间:
1995
影响因子:
3.5
通讯作者:
He Yizhen
He Yizhen
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Ding Xingzhao;L. Ju;Qi Zhenzhong;He Yizhen

文献摘要

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研究了水解催化剂(HCl和C5H8O2)对凝胶法制备纳米TiO2粉体结构的影响。HCl催化的凝胶的结晶温度比C5H8O2催化的凝胶的结晶温度低约200 K。但在后一种凝胶中,金红石相在较低的温度下转变为金红石相,并且转变在更窄的温度范围内完成。
Effect of hydrolysis catalysts (HCl and C5H8O2) on structural evaluation of gelderived nanocrystalline TiO2 powders was studied. Crystallization temperature of the HCl catalyzed gel is about 200 K lower than that of the C5H8O2 catalyzed one. But in the later gel the anatase phase transforms to rutile at a lower temperature, and the transformation is completed in a much more narrow temperature range.