Preparation, Use, and Safety of O-Mesitylenesulfonylhydroxylamine
Preparation, Use, and Safety of O-Mesitylenesulfonylhydroxylamine
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DOI：
10.1021/op800264p
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发表时间：
2009-03-01
影响因子：
3.4
通讯作者：
Davis, Edward M.
中科院分区：
文献类型：
--
作者：
Mendiola, Javier;Rincon, Juan A.;Davis, Edward M.
胺化试剂O-均三甲苯磺酰羟胺（MSH）具有已知的潜在危害，因为其结构中含有高能官能团。文献中有参考文献报告了涉及使用纯和结晶MSH的几起事件。本文描述了该试剂在公斤级规模上的制备和安全使用。
The aminating reagent O-mesitylsulfonylhydroxylamine (MSH) has a known potential hazard since it contains high-energy functional groups in its structure. There are references in the literature that report several incidents involving the use of pure and crystalline MSH. The preparation and safe use of this reagent at kilo scale are described herein.