SELF-ASSEMBLED MONOLAYERS OF ALKANETHIOLS CONTAINING A POLAR AROMATIC GROUP - EFFECTS OF THE DIPOLE POSITION ON MOLECULAR PACKING, ORIENTATION, AND SURFACE WETTING PROPERTIES
SELF-ASSEMBLED MONOLAYERS OF ALKANETHIOLS CONTAINING A POLAR AROMATIC GROUP - EFFECTS OF THE DIPOLE POSITION ON MOLECULAR PACKING, ORIENTATION, AND SURFACE WETTING PROPERTIES
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DOI：
10.1021/ja00011a010
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发表时间：
1991-05-22
影响因子：
15
通讯作者：
FERRIS, N
中科院分区：
文献类型：
--
作者：
EVANS, SD;URANKAR, E;FERRIS, N
利用椭圆偏振、润湿、反射吸收FTIR、表面接触电位和表面增强拉曼光谱等多种技术研究了芳香族基团引入烷硫醇自组装单分子膜的影响。单分子膜的质量取决于引入到薄膜中的偶极的大小和芳香基团上方的脂肪链的长度。
The effect of incorporating aromatic groups into self-assembled alkanethiol monolayers was studied using a variety of techniques including ellipsometry, wetting, reflection-absorption FTIR, surface (contact) potential, and surface enhanced Raman spectroscopy (SERS). The quality of the monolayers produced was found to be dependent on both the size of the dipole introduced into the film and the length of the aliphatic chain above the aromatic group.