KINETICS OF NUCLEATION IN NEAR-CRITICAL FLUIDS
KINETICS OF NUCLEATION IN NEAR-CRITICAL FLUIDS
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DOI：
10.1103/physreva.21.948
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发表时间：
1980-01-01
影响因子：
2.9
通讯作者：
SCHWARTZ, AJ
中科院分区：
文献类型：
--
作者：
LANGER, JS;SCHWARTZ, AJ
提出了一组简单的速率方程来描述亚稳态近临界流体中液滴的成核和生长。这些方程与稳态成核理论一起用于计算二元混合物中相分离的完成时间。重新检查现有的实验数据提供了很少的证据，如果有任何证据的主要失败的传统成核理论，已假定在这些数据的基础上。
A simple set of rate equations is proposed to describe nucleation and growth of droplets in metastable, near-critical fluids. These equations are used in conjunction with steady-state nucleation theory to compute completion times for phase separation in binary mixtures. Reexamination of available experimental data provides little if any evidence for the major failure of conventional nucleation theory that has been postulated on the basis of these data.