Hierarchical porous silica materials with a trimodal pore system using surfactant templates

Hierarchical porous silica materials with a trimodal pore system using surfactant templates
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DOI:
10.1021/ja0470618
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发表时间:
2004-09-01
影响因子:
15
通讯作者:
Smarsly, B
Smarsly, B
中科院分区:
化学1区
文献类型:
--
作者:
Kuang, DB;Brezesinski, T;Smarsly, B

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以聚苯乙烯乳胶球、一种新型嵌段共聚物和一种离子液体表面活性剂为模板剂,制备了具有三峰结构的多孔二氧化硅。所得材料在三个长度尺度(小中孔:2 - 3 nm;大中孔:11 - 12 nm;大孔:360 nm)下表现出分级顺序。
Porous silica exhibiting a hierarchically ordered trimodal pore system with a well-defined reverse opal microstructure and bimodal mesoporosity in the walls has been prepared by using polystyrene latex spheres, a novel block copolymer and an ionic liquid surfactant as templates. The resulting materials exhibit hierarchical order at three length scales (small mesopores:  2−3 nm; large mesopores:  11−12 nm; macropores:  360 nm).