Aromatic-Diimide-Based n-Type Conjugated Polymers for All-Polymer Solar Cell Applications.
Aromatic-Diimide-Based n-Type Conjugated Polymers for All-Polymer Solar Cell Applications.
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用于全聚合物太阳能电池应用的基于芳香族二酰亚胺的 n 型共轭聚合物。
DOI：
10.1002/adma.201804699
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发表时间：
2018
影响因子：
29.4
通讯作者：
Zhou Erjun
中科院分区：
文献类型：
--
作者：
Yang Jing;Xiao Bo;Tang Ailing;Li Jianfeng;Wang Xiaochen;Zhou Erjun
近年来，全聚合物太阳能电池（全聚合物太阳能电池）因其供体和受体聚合物的吸收光谱和电子能级可调的优势，以及其优越的上级热稳定性和机械稳定性而引起了人们的极大关注。新型n型共轭聚合物（CPs）的开发，特别是基于芳香族二酰亚胺（ADI）的新型n型共轭聚合物的开发，对于进一步提高全PSC的功率转换效率（PCE）起着至关重要的作用。本文综述了萘二酰亚胺（NDI）、苝二酰亚胺（PDI）及其衍生物等ADI的结构修饰研究进展，揭示了ADI基CP的结构与性能关系。
All‐polymer solar cells (all‐PSCs) have attracted immense attention in recent years due to their advantages of tunable absorption spectra and electronic energy levels for both donor and acceptor polymers, as well as their superior thermal and mechanical stability. The exploration of the novel n‐type conjugated polymers (CPs), especially based on aromatic diimide (ADI), plays a vital role in the further improvement of power conversion efficiency (PCE) of all‐PSCs. Here, recent progress in structure modification of ADIs including naphthalene diimide (NDI), perylene diimide (PDI), and corresponding derivatives is reviewed, and the structure–property relationships of ADI‐based CPs are revealed.