Spontaneous symmetry-breaking in halogen-bonded, bent-core liquid crystals: observation of a chemically driven Iso-N-N* phase sequence.

Spontaneous symmetry-breaking in halogen-bonded, bent-core liquid crystals: observation of a chemically driven Iso-N-N* phase sequence.
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DOI:
10.1039/b719555a
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发表时间:
2008-04
影响因子:
4.9
通讯作者:
C. Präsang;A. Whitwood;D. Bruce
C. Präsang;A. Whitwood;D. Bruce
中科院分区:
化学2区
文献类型:
--
作者:
C. Präsang;A. Whitwood;D. Bruce

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在卤素键合的弯曲核介元中观察到手性向列相,它本身是非手性的;相序列源于卤素键合络合物的不稳定性。
A chiral nematic phase is observed in a halogen-bonded, bent-core mesogen, which is itself achiral; the phase sequence arises from the lability of the halogen-bonded complex.