Trilithium scandium bis-(orthoborate).

Trilithium scandium bis-(orthoborate).
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双(原硼酸)三锂钪

DOI:
10.1107/s1600536808014797
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发表时间:
2008-05-21
期刊:
Acta crystallographica. Section E, Structure reports online
影响因子:
--
通讯作者:
Ye N
Ye N
中科院分区:
其他
文献类型:
--
作者:
Mao L;Zhou T;Ye N

文献摘要

相似文献

用高温熔体自发成核法获得了标题化合物Li_3Sc(BO_3)_2的单晶。标题化合物为骨架结构,由畸变的[ScO 6]八面体、[LiO 4]四面体、[LiO 4]长方体和孤立的[BO 3]三角体组成。除了Sc和一个Li原子(都在反转中心上),所有原子都处于一般位置。
Single crystals of the title compound, Li3Sc(BO3)2, have been obtained by spontaneous nucleation from a high-temperature melt. The title compound adopts a framework structure and is composed of distorted [ScO6] octahedra, [LiO4] tetrahedra, [LiO4] rectangles and isolated [BO3] triangles. Except for the Sc and one Li atom (both on inversion centres), all atoms are in general positions.