Excited-State Dynamics of Catalytically Active Transition Metal Complexes Studied by Transient Photofragmentation in Gas Phase and Transient Absorption in Solution

Excited-State Dynamics of Catalytically Active Transition Metal Complexes Studied by Transient Photofragmentation in Gas Phase and Transient Absorption in Solution
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通过气相瞬态光碎裂和溶液瞬态吸收研究催化活性过渡金属配合物的激发态动力学

DOI:
10.1007/978-3-319-13242-6_92
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发表时间:
2014
期刊:
影响因子:
--
通讯作者:
C. Riehn
C. Riehn
中科院分区:
--
文献类型:
--
作者:
D. Imanbaew;Y. Nosenko;K. Chevalier;F. Rupp;C. Kerner;F. Breher;W. R. Thiel;R. Diller;C. Riehn

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飞秒光致碎裂(气相)和瞬态吸收(溶液)揭示了Ru(II)配合物中的超快电子耦合(0.1-3 ps)和能量转移(7-12 ps)以及Pd 3配合物中长寿命三重态的超快形成(~0.4 ps)。
Femtosecond photofragmentation (gas phase) and transient absorption (solution) revealed ultrafast electronic coupling (0.1–3 ps) and energy transfer (7–12 ps) in a Ru(II)-complex and ultrafast formation (~0.4 ps) of a long-lived triplet state in a Pd3-complex.
DOI: 10.1016/j.chemphys.2014.03.005
发表时间: 2014
期刊: Chemical Physics
影响因子: 2.3
作者:
D. Imanbaew;Y. Nosenko;C. Kerner;K. Chevalier;F. Rupp;C. Riehn;W. R. Thiel;R. Diller
通讯作者: R. Diller