Novel Regio- and Stereo-Selectivity: Synthesis of Dihydropyrrolo[1,2-f]phenanthridines via Isocyanide-Based Multicomponent Reaction.
Novel Regio- and Stereo-Selectivity: Synthesis of Dihydropyrrolo[1,2-f]phenanthridines via Isocyanide-Based Multicomponent Reaction.
复制标题
DOI：
10.1002/chin.201139133
复制
发表时间：
2011-09
期刊：
影响因子：
--
通讯作者：
Ming Li;Zhongxuan Qiu;L. Wen;Zhongmin Zhou
中科院分区：
文献类型：
--
作者：
Ming Li;Zhongxuan Qiu;L. Wen;Zhongmin Zhou
在没有催化剂的情况下，菲啶、丙二腈和异腈以单一非对映体或高非对映选择性得到标题化合物，这取决于异腈的体积。
In the absence of a catalyst, phenanthridine, malononitriles and isocyanides give the title compounds as single diastereomers or with high diastereoselectivity, depending on the bulkiness of the isocyanide.