Sustainable ammonia synthesis: Just around the corner?
Sustainable ammonia synthesis: Just around the corner?
复制标题
可持续氨合成：指日可待？
DOI：
10.1016/j.joule.2022.09.001
复制
发表时间：
2022
期刊：
影响因子：
39.8
通讯作者：
Manthiram, Karthish
中科院分区：
文献类型：
--
作者：
Klein, Channing K.;Manthiram, Karthish
Li介导氨的电化学合成已被提出作为对环境有害且需要集中操作的Haber-Bosch工艺的一种可能的替代方案。然而，它在历史上一直受到低法拉第效率、速度和电流密度的困扰。在本期《焦耳》杂志中，乔肯多夫和他的同事展示了一种符合某些工业基准的过程版本，并揭示了一路上反应动力学的新见解。麦克法兰和他的同事最近在《自然》杂志上的一项研究证实了他们的观察结果，该研究还证明了极高的法拉第效率和氨合成的高速率。
Li-mediated electrochemical synthesis of ammonia has been put forward as a possible alternative to the Haber-Bosch process, which is harmful to the environment and requires centralized operation. However, it has historically been plagued by low Faradaic efficiency, rate, and current density. In this issue ofJoule, Chorkendorff and co-workers present a version of the process that meets certain industrial benchmarks and unveil new insights into the reaction kinetics along the way. Their observations are borne out by a recent study inNaturefrom MacFarlane and co-workers which also demonstrates extremely high Faradaic efficiency and high rates toward ammonia synthesis.
影响因子：
37.8
作者：
Lazouski, Nikifar;Chung, Minju;Manthiram, Karthish
通讯作者：
Manthiram, Karthish