A high-performance recycling solution for polystyrene achieved by the synthesis of renewable poly(thioether) networks derived from D-limonene.
A high-performance recycling solution for polystyrene achieved by the synthesis of renewable poly(thioether) networks derived from D-limonene.
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DOI：
10.1002/adma.201304370
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发表时间：
2014-03-12
影响因子：
29.4
通讯作者：
Maitland, Duncan J.
中科院分区：
文献类型：
--
作者：
Hearon, Keith;Nash, Landon D.;Rodriguez, Jennifer N.;Lonnecker, Alexander T.;Raymond, Jeffery E.;Wilson, Thomas S.;Wooley, Karen L.;Maitland, Duncan J.
纳米复合聚合物已使用新型可持续材料合成工艺制备，其中d-柠檬烯同时用作回收聚苯乙烯（PS）废物的溶剂和单体，与多硫醇共聚单体进行紫外线催化的硫醇-烯聚合反应，以提供由分散在整个弹性体聚（硫醚）网络中的沉淀PS相组成的聚合物产品。这些共混网络表现出的机械性能大大超过单独的聚苯乙烯或聚（硫醚）网络均聚物。
Nanocomposite polymers have been prepared using a new sustainable materials synthesis process in which d-Limonene functions simultaneously both as a solvent for recycling polystyrene (PS) waste and as a monomer that undergoes UV-catalyzed thiol-ene polymerization reactions with polythiol co-monomers to afford polymeric products comprised of precipitated PS phases dispersed throughout elastomeric poly(thioether) networks. These blended networks exhibit mechanical properties that greatly exceed those of either polystyrene or the poly(thioether) network homopolymers alone.
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影响因子：
4.6
作者：
Nair, Devatha P.;Cramer, Neil B.;Scott, Timothy F.;Bowman, Christopher N.;Shandas, Robin
通讯作者：
Shandas, Robin
DOI：
10.1016/j.jmatprotec.2008.07.017
发表时间：
2009-03-19
影响因子：
6.3
作者：
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影响因子：
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作者：
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影响因子：
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作者：
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通讯作者：
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影响因子：
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作者：
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通讯作者：
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