Synthesis of vinyl thioethers and bis-thioethenes from calcium carbide and disulfides
Synthesis of vinyl thioethers and bis-thioethenes from calcium carbide and disulfides
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DOI：
10.1016/j.mencom.2017.09.015
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发表时间：
2017-09
影响因子：
1.9
通讯作者：
K. Rodygin;Yuliya V. Gyrdymova;V. Zarubaev
中科院分区：
文献类型：
--
作者：
K. Rodygin;Yuliya V. Gyrdymova;V. Zarubaev
以二硫化物和电石为原料，采用简单的合成方法和常用的实验室设备，以较高的收率制备了双硫乙烯和乙烯基硫醚。以脂肪族、芳香族、杂芳香族和倍半萜为底物考察了反应的耐受性。
Bis-thioethenes and vinyl thioethers were obtained from the reaction of disulfides and calcium carbide in good to high yields using a simple synthetic procedure and common laboratory setup. The tolerance of the reaction was investigated by the examples of aliphatic, aromatic, heteroaromatic and sesquiterpenic substrates.