Effect of dissolved LiCl on the ionic liquid-Au(111) electrical double layer structure
Effect of dissolved LiCl on the ionic liquid-Au(111) electrical double layer structure
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DOI：
10.1039/c2cc35737b
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发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Atkin, Rob
中科院分区：
文献类型：
--
作者：
Hayes, Robert;Borisenko, Natalia;Atkin, Rob
在离子液体（IL）-Au（111）界面处的双电层由交替的离子层组成。当少量LiCl溶解在IL中时，对于-2.0 V和+2.0 V（相对于Pt）之间的所有电位，界面分层明显较弱。这意味着，纯IL电双层开发的模型可能是无效的，当溶质存在。
The electrical double layer at ionic liquid (IL)-Au(111) interfaces is composed of alternating ion layers. Interfacial layering is markedly weaker when small amounts of LiCl are dissolved in the IL for all potential between -2.0 V and +2.0 V (vs. Pt). This means that models developed for pure IL electrical double layers may not be valid when solutes are present.