An Efficient Enantioselective Synthesis of Blastmycinone.

An Efficient Enantioselective Synthesis of Blastmycinone.
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DOI:
10.1002/chin.200612235
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发表时间:
2005-11
期刊:
ChemInform
影响因子:
--
通讯作者:
Yong‐Qing Yang;Yikang Wu
Yong‐Qing Yang;Yikang Wu
中科院分区:
其他
文献类型:
--
作者:
Yong‐Qing Yang;Yikang Wu

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Blastmycinone, a degradation product of the antibiotic antimycin A, was synthesized with a TiCl4-mediated asymmetric aldolization as the key step. Some unexpected yet interesting chemistry was also observed.