Synthesis of chiral, enantiopure zirconocene imido complexes: highly selective kinetic resolution and stereoinversion of allenes, and evidence for a stepwise cycloaddition/retrocycloaddition reaction mechanism.
Synthesis of chiral, enantiopure zirconocene imido complexes: highly selective kinetic resolution and stereoinversion of allenes, and evidence for a stepwise cycloaddition/retrocycloaddition reaction mechanism.
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手性对映体纯二茂锆亚氨基配合物的合成:丙二烯的高选择性动力学拆分和立体反转,以及逐步环加成/逆环加成反应机制的证据。
DOI:
10.1002/1521-3773(20000703)39:13
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发表时间:
2000
期刊:
影响因子:
--
通讯作者:
Bergman,RG
中科院分区:
文献类型:
--
作者:
Sweeney,ZK;Salsman,JL;Andersen,RA;Bergman,RG
Certain metal±carbon multiple bonds exhibit substantial reactivity toward organic compounds and are important intermediates in many catalytic processes.[1] The analogous reactivity of metal±heteroatom multiple bonds, such as those in metal±imido complexes, has been known for a much shorter time and has only relatively recently been utilized in synthetic applications.[2]
DOI:
--
发表时间:
1980
期刊:
American journal of ophthalmology-glaucoma
影响因子:
--
作者:
D. Meisler;C. R. Zaret;E. Stock
通讯作者:
E. Stock
DOI:
--
发表时间:
1981
期刊:
A M A Archives of Ophthalmology
影响因子:
--
作者:
P. Binder;D. M. Rasmussen;M. Gordon
通讯作者:
M. Gordon