Metal-organic framework based mixed matrix membranes: a solution for highly efficient CO2 capture?
Metal-organic framework based mixed matrix membranes: a solution for highly efficient CO2 capture?
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DOI：
10.1039/c4cs00437j
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发表时间：
2015-04-21
影响因子：
46.2
通讯作者：
Gascon J
中科院分区：
文献类型：
--
作者：
Seoane B;Coronas J;Gascon I;Etxeberria Benavides M;Karvan O;Caro J;Kapteijn F;Gascon J
综述了金属-有机骨架混合基质膜（M4 s）的研究进展，重点介绍了其在能源生产过程中CO2捕集方面的应用。综述了金属-有机骨架混合基质膜（M4 s）的研究进展，重点介绍了其在能源生产过程中CO2捕集方面的应用。在介绍了影响膜性能的最相关参数后，我们根据燃烧前和燃烧后CO2捕获工艺设计的现有文献，定义了选择性和生产率方面的目标。随后，根据这些目标审查了M4的最新技术水平。由于这些膜的最终应用将只可能，如果薄的分离层可以生产，在M4中空纤维制造的最新进展进行了讨论。最后，总结了近年来在这些复杂复合材料分离性能方面所做的工作，并展望了今后的研究方向。
The field of metal–organic framework based mixed matrix membranes (M4s) is critically reviewed, with special emphasis on their application in CO2 capture during energy generation. The field of metal–organic framework based mixed matrix membranes (M4s) is critically reviewed, with special emphasis on their application in CO2 capture during energy generation. After introducing the most relevant parameters affecting membrane performance, we define targets in terms of selectivity and productivity based on existing literature on process design for pre- and post-combustion CO2 capture. Subsequently, the state of the art in M4s is reviewed against these targets. Because final application of these membranes will only be possible if thin separation layers can be produced, the latest advances in the manufacture of M4 hollow fibers are discussed. Finally, the recent efforts in understanding the separation performance of these complex composite materials and future research directions are outlined.