Efficient PdNi and PdNi@Pd-catalyzed hydrogen generation via formic acid decomposition at room temperature

Efficient PdNi and PdNi@Pd-catalyzed hydrogen generation via formic acid decomposition at room temperature
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DOI:
10.1039/c3cc46248j
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发表时间:
2013-01-01
影响因子:
4.9
通讯作者:
Zhang, Xin-bo
Zhang, Xin-bo
中科院分区:
化学2区
文献类型:
--
作者:
Qin, Yu-ling;Wang, Jun;Zhang, Xin-bo

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甲酸(FA)作为可持续化学合成和可再生能源储存的方便氢源具有巨大的潜力。在此,非贵金属镍(Ni)在提高Pd的催化活性方面表现出上级的促进作用,从而在室温下对FA分解具有高活性和选择性。
Formic acid (FA) holds great potential as a convenient source of hydrogen for sustainable chemical synthesis and renewable energy storage. Herein, the non-noble metal nickel (Ni) exhibits superior promoting effect in improving the catalytic activity of Pd toward high activity and selectivity for FA decomposition at room temperature.