Tailor-made Covalent Organic-Inorganic Polyoxometalate Hybrids: Versatile Platforms for the Elaboration of Functional Molecular Architectures
Tailor-made Covalent Organic-Inorganic Polyoxometalate Hybrids: Versatile Platforms for the Elaboration of Functional Molecular Architectures
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DOI：
10.1002/tcr.201600092
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发表时间：
2017-02-01
期刊：
影响因子：
6.6
通讯作者：
Proust, Anna
中科院分区：
文献类型：
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作者：
Izzet, Guillaume;Volatron, Florence;Proust, Anna
有机修饰多金属氧酸盐（pom）的后功能化是设计功能模块以合理制备pom基分子材料的有力合成工具。在这篇个人文章中，我们专注于碘芳基端端POM平台，描述了合成共价有机-无机POM基杂化物的可靠途径，以及它们与先进分子结构或多尺度组装的集成，以及它们在表面上的固定。在人工合成和分子电子学领域中，对聚甲醛优异的氧化还原性能进行了评价。
Post-functionalization of organically modified polyoxometalates (POMs) is a powerful synthetic tool to devise functional building blocks for the rational elaboration of POM-based molecular materials. In this personal account we focus on iodoaryl-terminated POM platforms, describe reliable routes to the synthesis of covalent organic-inorganic POM-based hybrids and their integration into advanced molecular architectures or multi-scale assemblies as well as their immobilization onto surfaces. Valorisation of the remarkable redox properties of POMs in the fields of artificial synthesis and molecular electronic is especially considered.